Sounds like you have no backup. FIRST STEP, BACKUP THE DATA!
If you currently have a working RAID-1 array, I'd connect one of the new drives to the computer and use it to create a backup first.
Next, with that backup in hand, connect one of the 1TB drives and move your backup to that drive.
Finally, stick both new 2TB drives in the NAS and build your RAID-1 array, copy your backup over.
Note that you should still have a separate backup, RAID of any level is NOT backup!