No, unless such option will be implemented in firmware.
Perhaps if you have 2 servers you should use load balancing http server (lighthttp) and clusters for sql?
I have never meet such option, perhaps reason why is that normally you never use secondary server in this case, I mean for a lot of time it become useless server. Servers should work 24/7 so no big deal. But what you are trying to do is possible for DNS. For example free domain services like no-ip.com. Just setup domain and in option setup Offline Options Web Redirect if on this same IP use different port for http server and forward this port on different internal IP. But I recommend free web hosting server, or better friend server.