Not without hacking the unit - and there's more to it than just a male-male cable.
USB requires "master/slave" pairs - in which the master or host is the controller, and the slave is the device - so your computer or the NAS would be a master, and the printer would be a slave - you're trying to connect two masters to one another, which doesn't work - you need a transfer cable which acts as the slave to both devices and you'll need drivers, that work with an arm based linux OS and a way to install them.