The DNS-325 does not support RAID resizing. The size of the smallest HDD when the RAID 1 array was originally created determines the size of the RAID volumes. Adding a larger capacity HDD later will not resize the array.
Example: If your RAID 1 array originally consisted of: 160GB and 2TB HDDs, the RAID 1 array will create two volumes of size 160GB and 160GB. If you swap the 160GB with a new 2TB HDD, the RAID array will still maintain two volumes of 160GB and 160GB even though there are two 2TB HDDs.
If you are planning on creating a RAID 0 array, I strongly suggest you create a full backup of your data on another physical storage device. If one HDD fails in your RAID 0 array, you will lose 100% of your data. Assuming you have a backup (and if you don't you should create one), you can reconfigure your HDDs from scratch to create the RAID 0 array.
You can attach the 2 TB HDDs in a Windows PC and delete the partitions so the DNS-320 won't recognize the previous formatting, then you should be able to configure everything from scratch.