For a start I would recommend RAID 1 rather than RAID 0. RAID 1 will save your data if a disk dies where RAID 0 will not and, of course, neither replaces a good tested backup.
The best way you transfer your data back is to use your up to date backup - this also proves your backup works.
From your question, I am assuming you don't have a backup so you will need to either transfer everything on your disks to your computer or get a USB/SATA adapter or caddy. If you go the USB/SATA adapter route read the sticky 'DNS-320-Data recovery (windows PCs)' at the head of this forum.
With a little care you should have no problems.