The 323 really isn't designed with AD in mind, and short of disabling SMB Signing and setting the 323's workgroup to be the same as your domain name (*), there aren't many good suggestions out there.
NIS isn't supported or provided on the 323 - which makes Unix user & group mapping a very manual process. It's a b*tch to setup anyway -- had to do this at work for three servers running VMWare ESX Server 3.5. Plus, even if you got it set up on one machine, you would have to manually go out and set it up on every other machine *because* you can't re-share a Unix Share from your SBS. Oh, and you have to install the Subsystem for Unix Applications on every system to get the nfsmgmt.msc Console so you can do the mapping. Total TimeWaster™
* Don't forget your usernames & groups in AD must not have spaces in them if you want the 323 to map them properly to its internal users & groups list.
Pretty Bleak for AD support, I'm afraid.
Microsoft made things difficult for Li/Unix. There really aren't many small, inexpensive, and redundant storage devices for Small Businesses (staff of < 50). Windows Home Server doesn't have AD support; it's a really stripped down version of Windows Storage Server, so that's not what you need either. Perhaps if I had some insight as to what hardware your SBS is made of, then I could make a better "Microsoft" suggestion.
Going down the USB/Firewire path, something like this is a great idea:
http://www.newegg.com/Product/Product.aspx?Item=N82E16822136137
It's internally RAIDed for your mirroring pleasure and because it's a Windows-native device you won't have to worry about Linux or NFS or SAMBA.
Travis