Thanks guys.
I'll try moving the NAS next to the PC and see what happens. Was planning this anyway, but it's a bit of a logistical exercise. Also, it's not a permanent solution because the Media streamer for my TV is next to where the NAS currently resides, so if it is the homeplug network, I'll have to either put up with slow transfers or no media streaming!
Thanks for pointing out the issue with the GetNet, you seem to be right. Wonder where I'd got the idea it supported jumbo frames from, because I can't find that info now! Maybe I'll swap the switches around when I move the NAS to test, so that the switch that has jumbo frame support is between the PC and NAS.
In short, though, nobody can see any reason why I shouldn't be getting better speed out of this kit, other than what's been discussed?