OK, a little progress.
The 192.168.0.32 is the default IP address of the DNS-323 which is to be expected because you did a reset. I assume your network is on the 192.168.0.xxx subnet and 192.168.0.32 is outside the DHCP range of the DHCP server of the router - if it isn't then that needs correcting for a start.
The fact that NETSCAN does not show the default name of the DNS-323 is a concern.
One other thing you could try. Disconnect everything from the router except the first switch, then connect the PC to the switch and confirm it gets an IP address (Hoover IP is good for that). Then connect the DNS-323 to the switch and see if the Easy Search Utility (on the DNS-323 setup CD) can find the unit. If it can then you should be able to access the web interface and make any necessary adjustments. If the search utility can't find the NAS then we have to start thinking that there is either a faulty switch or the DNS-323 itself may have a fault.
As a side note, the possible reason the NAS appeared overnight is that it first looks for a DHCP assigned IP before reverting to the default IP but I don't know what the timeout is before it goes to default (we have never had cause to see this because all the NAS/switch setups we have at clients have fixed IP for the NAS).