Now we're getting somewhere, this appears to simply be a Windows issue, nothing really to do with the NAS.
How about posting this.
Hold the Windows key and press R, then type CMD then press Enter to open a command prompt:
In the command prompt window that opens, type type the following commands, one at a time, followed by the Enter key:
Note that there is a space before the -n or the /ALL, but there is NOT a space after the - or / in the following commands.
NBTSTAT -n
IPCONFIG /ALL
Right click in the command window and choose Select All, then hit Enter to copy the contents to the clipboard.
Paste the results in a message here.
If you are on a machine with no network connection, use a floppy, USB disk, or a CD-RW disk to transfer a text file with the information to allow pasting it here.