Do not - if you are running JBOD - even think of removing a drive without somehow making a backup, you WILL end up losing the data on both disks - if you had a disk fail, the data on the remaining disk should continue to be available, upto the first reboot, but after that, it will no longer be accessible.
Although I'm not familiar with the "switches" you're specifying in the xcopy command line, as you say xcopy works, and it'll probably do what you need, as well as anything else can.