Forget the idea of a disk image, it isn't going to work because of the bad sectors will have destroyed parts of your data.
What you should be doing is copying everything you can from the array onto backup disks, that is assuming you don't have a current backup of your data.
Once you have a backup of all the data that you can get, run the disk manufacturers test tools against both disks. This should tell you if the bad sectors are going to be a continuing problem - I tend to think that disk is a write off for reliable storage if you are seeing bad sectors because the firmware usually takes care of moving bad sectors to reserve sectors and bringing them on line.
When you know the state of the drives you have the decision to make - replace both or just the one. Whichever decision you make let the DNS-323 format the drives and then restore the data from your backup.