Just an idea:
Smart checks the hardware status of the drive. But nevertheless the hardware is 100% ok, it is possible that your mirror is no longer consistant. (I hope your drives are mirrored) Or the filsystem on the drive has bad blocks. (Caused by the power drop in the middle of a write cycle)
If the NAS does not provide a repair tool (like file system check) to fix this, the only way to solve that problem is to backup the NAS, reformat the drives. Create the logical volume again and restore the data.
If there is a problem on the filesystem, it can happen that the backup on one or more files fails.
This files are lost, but all the rest should be ok. I hope your backup tool is able to continue after bad files.
As long as you do not use the broken files, your NAS seems to be consistant.
As I said, just an idea!