I sync through one of my computers as well. I have a DNS-323 that contains mostly backups from a bunch of systems. I also have a DNS-321 that is strictly for backup of the DNS-323, once a week an automated script wakes up my machine in the middle of the night and synchronizes the two NAS units.
Any data on either of these units is in at least one other location, most of the data is in at least two different locations on the network.