If you have no backup for the data on the 1.5TB drive, my advice is to forget about that option!
I suggest you put the 2TB drive in the DNS-323, put the 1.5TB drive in a USB enclosure, and use it for backup. Remember, RAID is NOT backup, and you appear to be in a dilemma precisely because you have no backup for your data!
Unless you run a high availability server, you'll be better off with EXT3 formatted single disks in the NAS and a separate enclosure for a complete backup of that data.