In case of routed subnet... You don't need dmz_gw at all, because used your wan_ip and wan_gw.
1) Objects > Address book > InterfaceAddresses
Set dmznet to your additional subnet in CIDR format
Set dmz_ip to one of IPs from your additional subnet (ex, first)
2) Interfaces > Ethernet > dmz
Use only dmz_ip and dmznet for IP and network, keep gateway blank
Keep "add route" checkboxes
3) Rules > IP rules
Add necessary Allow rules between wan and dmz