Terry,
Here is my honest opinion on how to perfrom this without making timer circuits. I normally leave my equipment on if there is a standby mode and I have my drives set for 30 minute hibernate. It's your call if you would like to turn it off every night.
Purchase an electronic timer that controls 115 VAC devices. Do not use a mechanical timer because if power goes out, time is all off. The electronic ones are normally under $10.00 and I have two for use with the living room lights. Set the OFF time for 5 AM and the ON time for 6 AM and plug the NAS into it.
Install the capacitor modification I described so when power is restored, the unit comes on.
Now for the tricky part and you may need to do some research but I think it's the best method...
Load Fun Plug on your NAS. Do a search with Google and you will find instructions for it. This will allow you to communicate to the linux OS on the NAS. What you now need to do is create something to force a shutdown at 6 PM every night. Try the command "shutdown -h 18:00". This tells the OS to shutdown at 6 PM. To test this command you could just send "sudo shutdown -h +2" which means wait 2 minutes and then shutdown. Fun Plug gives you options for the shutdown but I don't know if the unit will actually power off, but I think it will. Now for turning the unit on via software, I doubt that will happen. I like the timer myself but if it's possible to have a software timer turn it on, spread the wealth when you find out.
How would I expect this to work? ...
1) It's 10 AM and you are turning on your modded system.
2) 6 PM rolls around and the shutdown command turns off your NAS (I hope).
3) 5 AM occurs and since the capacitor power on trick needs power gone, this is what we do here.
4) 6 AM rolls around and we turn on power and the NAS powers up again.
5) and we go back to step 2
My NAS is currently backing up my computer so I can't pull the drives and install my test drive. And let me make a point here, if you have a spare SATA drive you can test with, do it! I can't afford to lose my data, or I guess I could since it's all backed up but moving it from DVDs back to the NAS is times consuming.
Another command is Halt but it's immediate. I'm sure there is some command or method to accomplish this.
Good Luck
-Joe
EDIT: I just tried shutdown and the command doesn't exist. Halt will stop normal activity but does not power down the machine. There is a set of 323 utils that looked like it had a shutdown command. Maybe that's the ticket.